SiC Optics

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Primary Features:

  • More efficient for lightweight mirrors than any other optical material
  • transmits heat 100x faster than glass
  • resists gravity deformation +4x more than glass
  • AOS can provide design services if needed

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Description & Features

Silicon Carbide (SiC) is an advanced composite ceramic material developed for applications in Aerospace, Semiconductor Lithography, and Astronomy. This unique material has the highest combination of thermal and mechanical stability of any material which can be optically polished making it perfect for high performance lightweight mirrors mounted on aircraft and spacecraft for imaging, laser targeting and communications applications. Silicon carbide is also used in commercial applications such as lightweight scan mirrors, semiconductor wafer handling, and reflective imaging systems. AOS has pioneered an industry-leading process for manufacturing SiC optics for industry, defense, and research applications. We produce more SiC optics than anyone else in North America.

Should you be considering SiC for your application?

Our applications engineers can assist you to answer this question but here are few notes for guidance. There are four things to consider regarding SiC for your application:  Component Mass,  Thermal Operating Environment,  Dynamic Environment, and Cost. SiC is not the answer to every application, however, you might be surprised to discover that SiC is often the most affordable solution in addition to being the right technical choice.

Applications Questions:
Key Metrics to consider
Does your mirror need to be lightweight? Ratio of Stiffness vs. Mass E/ρ
What is the thermal stability of your environment? Thermal Conductivity vs. Expansion Coefficient k/α
Will your mirror experience rapid accelerations? Flexural Strength, Elastic Modulus σ, E
How important is durability? Fracture Toughness (Kc), Chemical Durability Kc
What material will provide the best value? Cost and perfromance / value trade-offs $

SiC property summary

Types of SiC

There are many different types of SiC and dozens of SiC material manufacturers around the word. AOS works with all different types of SiC and draws materials from many suppliers around the world. Therefore, you don’t need to worry about getting restricted to a specific brand. We can advise which SiC is best for you, and present the best options for you.  Properties of SiC vary by the method in which the SiC is made. There are both technical, and commercial trades to consider. Its our job to sort this out for you.hc-pictures-aperture-optical-sciences-durham-2-004

Reaction Bonded and Reaction Sintered

Reaction bonding is achieved by pressing a mixture of silicon carbide powder, graphite, and a plasticizer into a preform. The plasticizer is then burned off leaving behind a porous product. These pores are then infiltrated with silicon. This silicon reacts with the carbon to form silicon carbide. The final product is a mixture of silicon, carbon, and reaction formed silicon carbide between the original silicon carbide particles. Reaction bonded silicon carbide has a low porosity (full density can be achieved but will contain a higher amount of residual silicon). Reaction Bonded SiC is made by many producers around the globe has the largest diversity of properties depending on the manufacturer’s unique process.

Sintered

Sintering is a process of forming a solid mass which employs heat and pressure to cause fusion of powdered particles to from structures. First silicon carbide powder is mixed with sintering aids, typically carbon and boron. This mixture is then pressed into a mold. This compact is then sintered in an inert atmosphere at temperatures below the melting point.

Hot Press Sintered (HIP)

Hot press sintering is the same process as sintering just with higher temperatures and pressures. Sintering aids such as carbon, boron, or alumina can be used to reduce required temperatures. This process creates a full density silicon carbide.

Reaction Sintered

This variation of the sintered process infiltrates silicon during sintering of a green-state form at approximately 1700K so that the carbon in the material powder reacts with silicon to become SiC. 100% of the carbon and silicon react leaving no residual carbon. Reaction sintered SiC has been demonstrated to yield extremely high flexural bending strength often twice that reported for most sintered SiC.

CVD

Chemical vapor deposition is used to produce ultra-high purity silicon carbide. This process is conducted by exposing a wafer to silicon and carbon containing precursors. These precursors are reduced at high temperatures to form silicon carbide, while the by-products are removed with gases. Chemical vapor deposition creates extremely high purity silicon carbide with excellent thermal conductivity. However, this process has the highest production costs and may result in high residual stresses. Properties are anisotropic due to the columnar grains formed during the process.

A variation of CVD SiC is “Chemical Vapor Composite” silicon carbide coined by Fantom Materials (formerly Trex Enterprises) and is created using a modified chemical vapor deposition process. The process is differentiated from standard CVD processing by adding high purity alpha-silicon carbide particles to the reactant chemical vapor stream. Chemical vapor composite silicon carbide has full density and ultra high purity. Also, the silicon carbide particles act as nucleation sites to create equiaxial and stress free grains. CVC material can be made into substantially thicker substrates as compared with CVD SiC.

Converted

Converted SiC Chemical Vapor Conversion is a process whereby structures and substrates are conventionally machined to near-net shape from graphite material. The graphite preform is then reacted with SiO in a chamber and converted to pure beta-phase silicon carbide with low porosity (which may be backfilled with silicon). A thin CVD SiC or Si coating is applied to result in an ultra lightweight, high purity substrate with excellent thermal conductivity. Also within this family of SiC is carbon fiber reinforced silicon carbide (C/SiC). The addition of carbon fiber “whiskers” enable a number of advantages that are manifested as increased bend strength, high fracture toughness, and electrical conductivity.

DSC08631

 

Description & Features

Silicon Carbide (SiC) is an advanced composite ceramic material developed for applications in Aerospace, Semiconductor Lithography, and Astronomy. This unique material has the highest combination of thermal and mechanical stability of any material which can be optically polished making it perfect for high performance lightweight mirrors mounted on aircraft and spacecraft for imaging, laser targeting and communications applications. Silicon carbide is also used in commercial applications such as lightweight scan mirrors, semiconductor wafer handling, and reflective imaging systems. AOS has pioneered an industry-leading process for manufacturing SiC optics for industry, defense, and research applications. We produce more SiC optics than anyone else in North America.

Should you be considering SiC for your application?

Our applications engineers can assist you to answer this question but here are few notes for guidance. There are four things to consider regarding SiC for your application:  Component Mass,  Thermal Operating Environment,  Dynamic Environment, and Cost. SiC is not the answer to every application, however, you might be surprised to discover that SiC is often the most affordable solution in addition to being the right technical choice.

Applications Questions:
Key Metrics to consider
Does your mirror need to be lightweight? Ratio of Stiffness vs. Mass E/ρ
What is the thermal stability of your environment? Thermal Conductivity vs. Expansion Coefficient k/α
Will your mirror experience rapid accelerations? Flexural Strength, Elastic Modulus σ, E
How important is durability? Fracture Toughness (Kc), Chemical Durability Kc
What material will provide the best value? Cost and perfromance / value trade-offs $

SiC property summary

Types of SiC

There are many different types of SiC and dozens of SiC material manufacturers around the word. AOS works with all different types of SiC and draws materials from many suppliers around the world. Therefore, you don’t need to worry about getting restricted to a specific brand. We can advise which SiC is best for you, and present the best options for you.  Properties of SiC vary by the method in which the SiC is made. There are both technical, and commercial trades to consider. Its our job to sort this out for you.hc-pictures-aperture-optical-sciences-durham-2-004

Reaction Bonded and Reaction Sintered

Reaction bonding is achieved by pressing a mixture of silicon carbide powder, graphite, and a plasticizer into a preform. The plasticizer is then burned off leaving behind a porous product. These pores are then infiltrated with silicon. This silicon reacts with the carbon to form silicon carbide. The final product is a mixture of silicon, carbon, and reaction formed silicon carbide between the original silicon carbide particles. Reaction bonded silicon carbide has a low porosity (full density can be achieved but will contain a higher amount of residual silicon). Reaction Bonded SiC is made by many producers around the globe has the largest diversity of properties depending on the manufacturer’s unique process.

Sintered

Sintering is a process of forming a solid mass which employs heat and pressure to cause fusion of powdered particles to from structures. First silicon carbide powder is mixed with sintering aids, typically carbon and boron. This mixture is then pressed into a mold. This compact is then sintered in an inert atmosphere at temperatures below the melting point.

Hot Press Sintered (HIP)

Hot press sintering is the same process as sintering just with higher temperatures and pressures. Sintering aids such as carbon, boron, or alumina can be used to reduce required temperatures. This process creates a full density silicon carbide.

Reaction Sintered

This variation of the sintered process infiltrates silicon during sintering of a green-state form at approximately 1700K so that the carbon in the material powder reacts with silicon to become SiC. 100% of the carbon and silicon react leaving no residual carbon. Reaction sintered SiC has been demonstrated to yield extremely high flexural bending strength often twice that reported for most sintered SiC.

CVD

Chemical vapor deposition is used to produce ultra-high purity silicon carbide. This process is conducted by exposing a wafer to silicon and carbon containing precursors. These precursors are reduced at high temperatures to form silicon carbide, while the by-products are removed with gases. Chemical vapor deposition creates extremely high purity silicon carbide with excellent thermal conductivity. However, this process has the highest production costs and may result in high residual stresses. Properties are anisotropic due to the columnar grains formed during the process.

A variation of CVD SiC is “Chemical Vapor Composite” silicon carbide coined by Fantom Materials (formerly Trex Enterprises) and is created using a modified chemical vapor deposition process. The process is differentiated from standard CVD processing by adding high purity alpha-silicon carbide particles to the reactant chemical vapor stream. Chemical vapor composite silicon carbide has full density and ultra high purity. Also, the silicon carbide particles act as nucleation sites to create equiaxial and stress free grains. CVC material can be made into substantially thicker substrates as compared with CVD SiC.

Converted

Converted SiC Chemical Vapor Conversion is a process whereby structures and substrates are conventionally machined to near-net shape from graphite material. The graphite preform is then reacted with SiO in a chamber and converted to pure beta-phase silicon carbide with low porosity (which may be backfilled with silicon). A thin CVD SiC or Si coating is applied to result in an ultra lightweight, high purity substrate with excellent thermal conductivity. Also within this family of SiC is carbon fiber reinforced silicon carbide (C/SiC). The addition of carbon fiber “whiskers” enable a number of advantages that are manifested as increased bend strength, high fracture toughness, and electrical conductivity.

DSC08631

Specifications

AOS produces both custom (build to print) SiC optics and also provides internal products such as satellite telescopes and industrial scan mirrors. Specifications for Scan mirrors can be found here.

Custom Products are available according to the following specifications:

FEATURES SPECIFICATIONS
Size 25 mm – 800 mm
Flatness /Form Error up to λ/100 RMS
Configurations Flats, Spheres, Aspheres
Material Options CVD, RB-SiC, CVC, C-SiC
Mounts SiC integrated Optostructures & Conventional mounts available
Systems Available Athermal Telescopes, Scanning Systems
Design Services Optical, FEA, Dynamic & Thermal Analysis
Coatings Al, Ag, Au & High Laser Damage Threshold Dielectic as needed
Mounting Inserts Potted invar inserts if needed, Helicoils if needed

AOS uses state of the art machining and robotic polishing for the most advanced silicon carbide optics produced today. Quality is guaranteed using high resolution interferometry and precision dimensional measurement of alignment features and mounting datums.

Low surface roughness is achieved on all material types either by direct polishing of CVD and Sintered materials or with SiC claddings applied to RB-SiC and Composite SiCs.

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Ordering Information

Send us your drawings or specifications and we’ll begin preparing a quote for you.

Contact us today here to speak with an applications engineer or use our quote request utility to submit your RFQ.

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